The Kappa Chapter was established on 11/08/1873 at Mercer University. This chapter is located in Macon, GA.
- Founder(s): J. L. Hardeman
- Charter: November 8, 1873, J. L. Hardeman
- Charter Members: Gordon Frenchie Sorrell, William Arnold Adams, Thomas Usher Butts, George Snider Birch, James Reynolds Duggan
- H. Carl Vinson – Initiated 1901 – Distinguished Congressman from Georgia, 50 years
- Dr. Ferrol A. Sams, Jr. – Initiated 1938 – Acclaimed author
- Rt. Reverend James L. Duncan – Initiated 1931 – Former Canon Clerk of the Works, Washington National Cathedral, Washington, D.C., former Bishop, Episcopal Diocese of Southeast Florida, 23rd Knight Commander of Kappa Alpha Order from 1955 to 1957
- W. Elliott Dunwody – Initiated 1909 – 21st Knight Commander of Kappa Alpha Order from 1946 to 1951